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NTA-3Na MSDS
The first part:Chemical Name
Product Name:Nitrilotriacetic acid
Synonyms:Triglycine
EINECS:205-355-7
CAS No.:139-13-9
Formula:C6H9NO6
Molecular Weight:191.14g/mol
The second part:Composition/information
Ingredient name:Nitrilotriacetic acid
Ingredients:≥99.0%
The third part:Hazards
Risk category:1.2Relevant identified uses of the substance or mixture and uses advised against
Identified uses:Laboratory chemicals,Manufacture of substances SECTION2:Hazards identification
2.1Classification of the substance or mixture
Classification according to Regulation(EC)No1272/2008
Acute toxicity,Oral(Category4),H302
Eye irritation(Category2),H319
Carcinogenicity(Category2),H351
For the full text of the H-Statements mentioned in this Section,see Section16.
Classification according to EU Directives67/548/EEC or1999/45/EC
R40
Xn Harmful R22Xi Irritant R36
Hazard statement(s):H302Harmful if swallowed.
H319Causes serious eye irritation. H351Suspected of causing cancer.
Precautionary statement(s):P281Use personal protective equipment as required.
P305+P351+P338IF IN EYES:Rinse cautiously with water for several minutes.Remove
contact lenses,if present and easy to do.Continue rinsing.
Supplemental Hazard:none
The fourth part:First aid measures
In case of skin contact:Wash off with soap and plenty of water.Consult a physician.
In case of eye contact:Rinse thoroughly with plenty of water for at least15minutes and consult a physicianIf swallowed:Never give anything by mouth to an unconscious person.Rinse mouth with water.Consult a physician.
If inhaled:If breathed in,move person into fresh air.If not breathing,give artificial respiration.Consult a physician.
The fifth part:Firefighting measures
Hazardous combustion
products:
Carbon monoxide,carbon dioxide,nitrogen oxides.
Extinguishing media:Use water spray,alcohol-resistant foam,dry chemical or carbon dioxide. Advice for firefighters:Wear self contained breathing apparatus for fire fighting if necessary.
The sixth part:Accidental release measures
Emergency treatment:Use of personal protective equipment.Avoid dust formation.Avoid breathing vapors,fumes or gases.
Ensure adequate ventilation.
Evacuation to a safe area.Avoid breathing dust.
The Seventh part:Handling and storage
Handling Precautions:Avoid contact with skin and eyes.Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage:Store in cool place.Keep container tightly closed in a dry and well-ventilated place.
Specific and use(s):none
The Eighth part:Exposure controls/personal protection Allowable
concentration:
Components with workplace control parameters
Exposure Controls:Operate in accordance with good industrial hygiene and safety regulations.Before breaks and at the end of the work of their hands.
Eye protection:Wear protective chemical safety glasses. Body protection:Wear protective overalls on infiltration.
Respiratory protection:When the dust in the air concentrations exceeding have to wear self-absorption filter respirators.Emergency rescue or evacuation,air respirator should be worn.
Other protection:Shower and change clothes after work.Attention to personal hygiene.
The Ninth part:Physical and chemical properties
The main ingredients:Pure product
Appearance:white crystalline powder.
pH:none
Melting freezing point:246℃(decomposition)
Boiling point and
boiling range:
none
Flash point:none
The Tenth part:Stability and reactivity
Reactivity:none
Chemical stability:none
Possibility of hazardous reactions:noneConditions to avoid:none
Incompatible
materials:
Strong oxidizing agents,Strong bases Hazardous
decomposition
products:
none
The Eleventh part:Toxicological information
Acute toxicity:LD50Oral-rat-male and female-1470mg/kg (OECD Test Guideline401)
Skin corrosion/irritation:Skin-rabbit
Result:No skin irritation-24h (OECD Test Guideline404)
Serious eye damage/eye irritation:Eyes-rabbit
Result:Irritating to eyes.-24h (OECD Test Guideline405)
Respiratory or skin sensitisation:guinea pig
Result:Does not cause skin sensitisation. (OECD Test Guideline406)
Germ cell mutagenicity:Mutagenicity(micronucleus test) mouse-male
Result:negative
Carcinogenicity:This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC,ACGIH,NTP,or EPA classification.The National Cancer Institute(NCI)has found clear evidence for
carcinogenicity.Found positive for carcinogenicity in EPA Genetox program.
Limited evidence of carcinogenicity in animal studies
IARC:2B-Group2B:Possibly carcinogenic to humans(Trisodium nitrilotriacetate)
Reproductive toxicity none Specific target organ toxicity-single exposure:
none Specific target organ toxicity-repeated
exposure:
none Aspiration hazard:none
Additional Information:Repeated dose toxicity-rat-male-Oral-No observed adverse effect level-9mg/kg
RTECS:MB8400000
The Twelfth part:Ecological information
Toxicity:Toxicity to fish flow-through test LC50-Pimephales promelas(fathead minnow)-127mg/l-96h
Toxicity to daphnia and other aquatic invertebratesstatic test EC50-Daphnia magna(Water flea)-560-1.000mg/l-48h Toxicity to algae static test EC50-Desmodesmus subspicatus (Scenedesmus subspicatus)->100mg/l-72h
Persistence and degradability:Biodegradability aerobic-Exposure time28d Result:96%-Readily biodegradable. (OECD Test Guideline302B)
Bioaccumulative potential:
none Mobility in soil:none
Results of PBT and vPvB assessment:PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects:none
The Thirteenth part:Disposal considerations
Waste treatment methods:
Offer surplus and non-recyclable solutions to a licensed disposal company.Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Contaminated packaging dispose of as unused
The Fourteenth part:Transport information
UN number:ADR/RID:-IMDG:-IATA:-
UN proper shipping name:ADR/RID:Not dangerous goods IMDG:Not dangerous goods IATA:Not dangerous goods
Transport hazard
class(es):
ADR/RID:-IMDG:-IATA:-
Packaging group ADR/RID:-IMDG:-IATA:-
Environmental hazards:ADR/RID:no IMDG Marine pollutant:no IATA:no Special precautions for
user:
none
The Fifteenth part:Regulatory information
Regulatory Information:For this product a chemical safety assessment was not carried out SECTION15:Regulatory information
This safety datasheet complies with the requirements of Regulation(EC) No.1907/2006.